曹约强  特聘研究员  博士生导师

电子邮箱：yqcao@ecust.edu.cn

通讯地址：上海市梅陇路130号 200237

个人简介

研究方向和成果

催化技术是现代化学工业的支柱，其中超过30%的化工过程涉及到加氢反应。工业催化加氢体系由于涉及复杂的串并联反应以及多级的催化剂结构，导致加氢催化剂理性设计及目标反应路径定向调控面临巨大挑战。聚焦高性能聚合物与高端化学品合成中涉及的不饱和烃、不饱和醛、酯类和硝基类化合物催化加氢体系，致力于反应机理与数据驱动的选择性加氢催化剂设计与优化，参与煤基乙二醇合成、乙炔选择性加氢等工业加氢催化剂的研发工作，部分成果获2022年中国化工学会基础研究成果奖一等奖、2021 年上海市产学研合作优秀项目奖一等奖。迄今发表论文 80 余篇，其中以(共同)第一/通讯作者身份在 J. Am. Chem. Soc.、Angew. Chem. Int. Ed. (3篇)、Nat. Commun. (3篇)、Engineering、ACS Catal. (4篇)、AIChE J. (5篇)、Chem. Eng. J. (2篇)、J. Catal. (5篇)等期刊上发表论文 40 余篇，申请专利 18件，其中授权9件。

近五年代表性论文：

1. Xiaohu Ge^#, Jun Yin^#, Zhouhong Ren^#, Kelin Yan, Yundao Jing, Yueqiang Cao*, Nina Fei, Xi Liu*, Xiaonan Wang*, Xinggui Zhou, Liwei Chen, Weikang Yuan, Xuezhi Duan*. Atomic Design of Alkyne Semihydrogenation Catalysts via Active Learning. Journal of the American Chemical Society 2024, 146, 7, 4993–5004. (JACS Spotlights)

2. Jiahang Xi^#, Kelin Yan^#,Ningchao Zhu, Xiaohu Ge*, Qiang Yuwen, Mingming Chen, Yueqiang Cao*, Hao Jiang, Xinggui Zhou, Xuezhi Duan. Ni Active Sites Isolated by Antimony Toward Enhanced Propyne Semi-Hydrogenation. AIChE Journal 2024, 70, e18416.

3. Weixiao Sun^#, Xiaohu Ge^#, Wei Du, Jianrong Zeng, Jianbo Ma, Wenyao Chen, Gang Qian, Yueqiang Cao*, Xuezhi Duan, Xinggui Zhou, Jing Zhang*. Kinetics and Mechanistic Insights into Selective Hydrogenation of Furfural to Furfuryl Alcohol over Ni–Ga Intermetallics. AIChE Journal 2024, 70, e18423.

4. Chang Yao, Wenhua Li, Yurou Li, Yueqiang Cao*, Jing Zhang, Gang Qian, Xinggui Zhou, Xuezhi Duan*. Atomically Dispersed Pt to Boost Adjacent Frustrated Lewis Pair for 2,6-Diamino-3,5-Dinitropyridine Hydrogenation.AIChE Journal 2024, 70, e18278.

5. Mingxing Ye^#, Yurou Li^#, Zhirong Yang^#, Chang Yao, Weixiao Sun, Xiangxue Zhang, Wenyao Chen, Gang Qian, Xuezhi Duan, Yueqiang Cao*, Lina Li*, Xinggui Zhou, Jing Zhang*. Ruthenium/TiO₂‐Catalyzed Hydrogenolysis of Polyethylene Terephthalate: Reaction Pathways Dominated by Coordination Environment. Angewandte Chemie International Edition 2023, 62, e202301024. (Hot Paper)

6. Kelin Yan, Yueqiang Cao*, Xiaohu Ge, Yurou Li, Jing Zhang, Xueqing Gong, Gang Qian, Xinggui Zhou, Xuezhi Duan*. Kinetics-Assisted Identification and Regulation of Active Sites for Pd-Catalyzed Propyne Selective Hydrogenation. AIChE Journal 2023;69(3), e17922.

7. Chang Yao, Wenhua Li, Yueqiang Cao*, Xiaohu Ge, Zhirong Yang, Gang Qian, Xinggui Zhou, Xuezhi Duan*. Mechanistic and Kinetics Insights into Structure Sensitivity of 2, 6-Diamino-3, 5-Dinitropiridine Hydrogenation over Ni Catalysts. Journal of Catalysis 2023, 421, 162-171.

8. Xiaohu Ge, Yueqiang Cao*, Kelin Yan, Yurou Li, Lihui Zhou, Sheng Dai, Jing Zhang, Xueqing Gong, Gang Qian, Xinggui Zhou, Weikang Yuan, Xuezhi Duan*. Increasing the Distance of Adjacent Palladium Atoms for Configuration Matching in Selective Hydrogenation. Angewandte Chemie International Edition 2022, 61, e202215225. (Hot Paper)

9. Xiaohu Ge, Mingying Dou, Yueqiang Cao*, Xi Liu*, Qiang Yuwen, Jing Zhang, Gang Qian, Xueqing Gong, Xinggui Zhou, Liwei Chen, Weikang Yuan, Xuezhi Duan*. Mechanism Driven Design of Trimer Ni₁Sb₂ Site Delivering Superior Hydrogenation Selectivity to Ethylene. Nature Communications 2022, 13, 5534. (Editors’ Highlights)

10. Kelin Yan, Yueqiang Cao*, Xiaohu Ge, Yurou Li, Jing Zhang, Xueqing Gong, Gang Qian, Xinggui Zhou, Xuezhi Duan*. Kinetics-Assisted Identification and Regulation of Active Sites for Pd-Catalyzed Propyne Selective Hydrogenation. AIChE Journal2023, 69: e17922.

11. Zhirong Yang^#, Yurou Li^#, Yueqiang Cao*, Xingqiang Zhao, Wenyao Chen, Jing Zhang, Gang Qian, Chong Peng*, Xueqing Gong, Xuezhi Duan. Al2O3 Microrods Supported Pd Catalysts for Semi-Hydrogenation of Acetylene: Acidic Properties Tuned Reaction Kinetics Behaviors. Chemical Engineering Journal 2022, 445, 136681.

12. Zuwei Luo, Xiaofeng Xu, Guilin Dong, Yueqiang Cao*, Shen Hu, Guanghua Ye, Yi-An Zhu, Jinghong Zhou*, Wei Li, Xinggui Zhou. Regulating Mesopore Structures of Support toward Enhanced Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate on Ag Catalysts. Chemical Engineering Journal 2022, 450, 138397.

13. Yurou Li^#, Kelin Yan^#, Yueqiang Cao*, Xiaohu Ge, Xinggui Zhou, Weikang Yuan, De Chen, Xuezhi Duan*. Mechanistic and Atomic-Level Insights into Semi-Hydrogenation Catalysis to Light Olefins. ACS Catalysis 2022, 12, 12138-12161.

14. Guilin Dong, Zuwei Luo, Yueqiang Cao*, Sainan Zheng, Jinghong Zhou, Wei Li*, Xinggui Zhou. Understanding Size-dependent Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Ag Catalysts Understanding Size-dependent Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Ag Catalysts. Journal of Catalysis 2021, 401, 252-261.

15. Yueqiang Cao^#, Xiaohu Ge^#, Yurou Li, Rui Si, Zhijun Sui, Jinghong Zhou, Xuezhi Duan^*, Xinggui Zhou. Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene. Engineering 2021, 7, 103-110.

16. Yueqiang Cao, Wenzhao Fu, Zhouhong Ren, Zhijun Sui, Jinghong Zhou, Jun Luo, Xuezhi Duan^*, Xinggui Zhou^*. Tailoring Electronic Properties and Kinetics Behaviors of Pd/N-CNTs Catalysts for Selective Hydrogenation of Acetylene. AIChE Journal 2020, 66, e16857.

17. Yueqiang Cao^#, Hao Zhang^#, Shufang Ji, Zhijun Sui, Zheng Jiang, Dingsheng Wang*, Francisco Zaera, Xinggui Zhou, Xuezhi Duan^*, Yadong Li. Adsorption Site Regulation to Guide Atomic Design of Ni–Ga Catalysts for Acetylene Semi-Hydrogenation. Angewandte Chemie International Edition 2020, 59, 11647–11652. (Hot Paper)

18. Yueqiang Cao, Jonathan Guerrero-Sańchez, Ilkeun Lee, Xinggui Zhou, Noboru Takeuchi, Francisco Zaera*. Kinetic Study of the Hydrogenation of Unsaturated Aldehydes Promoted by CuPt_x/SBA-15 Single-Atom Alloy (SAA) Catalysts. ACS Catalysis 2020, 10, 3431-3443.

19. Can Xiong, Lin Tian, Chunchun Xiao, Zhenggang Xue, Fangyao Zhou, Huang Zhou, Yafei Zhao, Min Chen, Qiuping Wang, Yunteng Qu, Yidong Hu, Wenyu Wang, Yan Zhang, Xiao Zhou, Zhiyuan Wang, Peiqun Yin, Yu Mao, Zhen-Qiang Yu*, Yueqiang Cao*, Xuezhi Duan, Lei Zheng*, Yuen Wu*. Construction of highly accessible single Co site catalyst for glucose detection. Science Bulletin 2020, 65, 2100-2106.

20. Yueqiang Cao, Bo Chen, Jonathan Guerrero-Sánchez, Ilkeun Lee, Xinggui Zhou, Noboru Takeuchi, Francisco Zaera*. Controlling Selectivity in Unsaturated Aldehyde Hydrogenation Using Single-Site Alloy Catalysts. ACS Catalysis 2019, 9, 9150-9157.

科研项目

  1. 国家科技部重点研发计划课题2022YFA1503502子课题，主持

2. 国家自然科学基金重点项目子课题，主持

3. 国家自然科学基金青年基金，主持

4. 云南贵金属实验室科技计划项目，主持

5. 上海市“超级博士后激励计划”，主持

6. GF项目子课题，主持

7. 中国博士后科学基金特别资助(站中)，主持

8. 中国博士后科学基金面上资助，主持

9. 国家科技部重点研发计划课题2018YFB0604704，研究骨干

10. 中石化等企业委托开发项目，主持

获奖与荣誉

  1. 2023年，上海市青年科技启明星（A类）

2. 2023年，第九届中国科协青年人才托举工程

3. 2023年，I&EC Research 2023 Class of Influential Researchers

4. 2022年，中国化工学会基础研究成果奖一等奖（排名第二）

5. 2021年，上海市产学研合作优秀项目奖一等奖（排名第六）

6. 2020年，中国石油和化学工业联合会CPCIF-Clariant可持续发展青年创新奖优秀奖

7. 2020年，上海市青年五四奖章集体

8. 2019年，中国化工学会杨光华新秀奖

申请/授权专利

  1. 负载型Ni-Ga-Pd催化剂及其制备方法与应用，ZL202010493989.X.

2. 高分散金属-氧化物双功能催化剂及其制备方法与应用，ZL202010542444.3.

3. 一种Pd-In金属间化合物催化剂及其制备方法与应用，ZL202211052126.4.

4. 甘油氢解生产1,3-丙二醇用催化剂及其制备方法和应用，ZL202410063657.6.

5. 一种Co-Sb-M三元金属间化合物催化剂及其制备方法与应用，ZL202410154894.3.

6. 一种合成乙交酯的方法，ZL202110675326.4.

7. 一种高纯丙交酯的制备方法及其在聚乳酸合成中的应用，ZL202311445304.4.

8. 一种分离乙二醇和1,2-丁二醇混合醇的变压精馏系统，ZL201921171170.0.

9. 一种负载型Ni-Sb催化剂及其制备方法与应用，CN114957107A.

10. 一种银硅催化剂的制备方法，银硅催化剂及其应用，CN112387306A.

11. 一种负载型Ni-In-M催化剂及其制备方法与应用，CN115888735A.

12. 一种蛋壳型银硅催化剂及其制备方法和应用，ZL202210462721.9.

13. 一种镍基双金属催化剂及其制备方法和应用，CN116273055A.

14. M-In₂O₃双功能催化剂在4,6-二硝基间苯二酚选择性加氢反应中的应用，CN116966903A.

15. 一种Ni-M单原子合金催化剂及其制备方法与应用，CN117654545A.

16. 一种有机膦酸修饰的贵金属催化剂及其制备方法与应用，CN117019139A.

17. 一种界面结构均一的Pt-MOX催化剂的制备方法与应用，CN117619380A.

18. 一种微通道连续合成2,6-二氨基-3,5-二硝基吡啶的方法，CN114957107A.